Rapid Gas Hydrate Formation—Evaluation of Three Reactor Concepts and Feasibility Study

Molecules

Heyko Juergen Schultz¹  Florian Filarsky¹  Julian Wieser¹ 

[1] Faculty of Chemistry, Chemical Engineering, University of Applied Sciences Niederrhein, Adlerstr. 32, 47798 Krefeld, Germany;

关键词: gas hydrates;    rapid gas hydrate formation;    natural gas storage;    gas separation and conditioning;    spray reactor;    injection;   

DOI  :  10.3390/molecules26123615

来源: DOAJ

【 摘 要 】

Gas hydrates show great potential with regard to various technical applications, such as gas conditioning, separation and storage. Hence, there has been an increased interest in applied gas hydrate research worldwide in recent years. This paper describes the development of an energetically promising, highly attractive rapid gas hydrate production process that enables the instantaneous conditioning and storage of gases in the form of solid hydrates, as an alternative to costly established processes, such as, for example, cryogenic demethanization. In the first step of the investigations, three different reactor concepts for rapid hydrate formation were evaluated. It could be shown that coupled spraying with stirring provided the fastest hydrate formation and highest gas uptakes in the hydrate phase. In the second step, extensive experimental series were executed, using various different gas compositions on the example of synthetic natural gas mixtures containing methane, ethane and propane. Methane is eliminated from the gas phase and stored in gas hydrates. The experiments were conducted under moderate conditions (8 bar(g), 9–14 °C), using tetrahydrofuran as a thermodynamic promoter in a stoichiometric concentration of 5.56 mole%. High storage capacities, formation rates and separation efficiencies were achieved at moderate operation conditions supported by rough economic considerations, successfully showing the feasibility of this innovative concept. An adapted McCabe-Thiele diagram was created to approximately determine the necessary theoretical separation stage numbers for high purity gas separation requirements.

【 授权许可】

Unknown