Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate

IUCrData

Rafael A. Adrian¹  Sara J. Ibarra¹  Hadi D. Arman² 

[1] Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio Texas 78209, USA;Department of Chemistry, The University of Texas at San Antonio, San Antonio Texas 78249, USA;

关键词: crystal structure;    silver atom;    isonicotinamide;    trifluoromethanesulfonate ions;    acetonitrile;    polymeric structure;   

DOI  :  10.1107/S2414314621010737

来源: DOAJ

【 摘 要 】

The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear molecular geometry. The formation of polymeric chains {[Ag(INAM)2]+}n, held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating acetonitrile molecules that interact the silver metal center via regium bonds.

【 授权许可】

Unknown