Crystals | |
Spin-Crossover in Iron(II) Complexes of N,N′-Disubstituted 2,6-Bis(Pyrazol-3-yl)Pyridines: An Effect of a Distal Substituent in the 2,6-Dibromophenyl Group | |
Eva Rentschler1  Luca M. Carrella1  Valentin V. Novikov2  Rinat R. Aysin2  Elizaveta K. Melnikova2  Yulia V. Nelyubina2  Igor A. Nikovskiy2  Dmitry Yu. Aleshin2  Alexander V. Polezhaev2  | |
[1] Johannes Gutenberg-Universität Mainz, Duesbergweg 10–14, 55128 Mainz, Germany;Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Str., 28, 119991 Moscow, Russia; | |
关键词: distal substituent; iron(II) complexes; molecular design; paramagnetic NMR spectroscopy; spin-crossover; X-ray diffraction; | |
DOI : 10.3390/cryst11080922 | |
来源: DOAJ |
【 摘 要 】
A series of new bis(pyrazol-3-yl)pyridines (LR) N,N′-disubstituted by 4-functionalized 2,6-dibromophenyl groups have been synthesized to study the effect of a distal substituent on the spin-crossover (SCO) behaviour of the iron(II) complexes [Fe(LR)2](ClO4)2 by variable-temperature magnetometry, NMR spectroscopy, and X-ray diffraction. The SCO-assisting tendency of the substituents with different electronic and steric properties (i.e., the bromine atom and the methyl group) in the para-position of the 2,6-dibromophenyl group is discussed. Together with earlier reported SCO-active iron(II) complexes with N,N′-disubstituted bis(pyrazol-3-yl)pyridines, these new complexes open the way for this family of SCO compounds to emerge as an effective ‘tool’ in revealing structure–function relations, a prerequisite for successful molecular design of switchable materials for future breakthrough applications in sensing, switching, and memory devices.
【 授权许可】
Unknown