Co-Pyrolysis Behaviors of the Cotton Straw/PP Mixtures and Catalysis Hydrodeoxygenation of Co-Pyrolysis Products over Ni-Mo/Al2O3 Catalyst

Catalysts

Jian Li¹  Xinning Lu¹  Derun Hua²  Yu Chen²  Mingde Yang²  Yulong Wu² 

[1] Gannan Normal University, Chemical Institute of Chemical Industry, Ganzhou 341000, China;Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;

关键词: biomass;    catalysis hydrodeoxygenation;    bio-oil;    synergy;   

DOI  :  10.3390/catal5042085

来源: DOAJ

【 摘 要 】

The doping of PP (polypropylene) with cotton straw improved the bio-oil yield, which showed there was a synergy in the co-pyrolysis of the cotton straw and PP at the range of 380–480 °C. In a fixed-bed reactor, model compounds and co-pyrolysis products were used for reactants of hydrodeoxygenation (HDO) over Ni-Mo/Al2O3. The deoxygenation rate of model compounds decreased over Ni-Mo/Al2O3 in the following order:alcohol > aldehyde > acetic acid > ethyl acetate. The upgraded oil mainly consisted of C11 alkane.

【 授权许可】

Unknown