Electrical Property Analysis of Textured Ferroelectric Polycrystalline Antimony Sulfoiodide Using Complex Impedance Spectroscopy

Materials

Marian Nowak¹  Piotr Szperlich¹  Anna Starczewska¹  Bartłomiej Toroń¹ 

[1] Institute of Physics–Center for Science and Education, Silesian University of Technology, Krasińskiego 8, 40-019 Katowice, Poland;

关键词: antimony sulfoiodide (SbSI);    ferroelectric;    impedance spectroscopy;    polycrystals;    temperature dependences;   

DOI  :  10.3390/ma14102579

来源: DOAJ

【 摘 要 】

Antimony sulfoiodide (SbSI) is a ferroelectric semiconductor with many interesting physical properties (optical, photoconductive, ferroelectric, piezoelectric, etc.). The electrical properties of textured polycrystalline SbSI obtained by the rapid cooling of a melted mass in liquid nitrogen are presented in this work using ac impedance spectroscopy over a wide temperature range (275–500 K) in the frequency range of 1 Hz to 100 kHz. Detailed studies of the impedance Z*(ω), conductivity σ*(ω), electric modulus M*(ω), and dielectric permittivity ε*(ω) of this material were performed using complex impedance spectroscopy for the first time. This study showed that the impedance and related parameters are strongly dependent on temperature. The internal domain structure and the presence of grain boundaries in textured polycrystalline SbSI explain the obtained results.

【 授权许可】

Unknown