Liquid gas phase transition at and below the critical point

Condensed Matter Physics

关键词: liquid-gas phase transition;    critical point;    collective variables;   

DOI  :  10.5488/CMP.16.23604

来源: DOAJ

【 摘 要 】

This article is a continuation of previous works (see Yukhnovskii I.R. et al., J. Stat. Phys, 1995, 80, 405 and references therein), where we have described the behavior of a simple system of interacting particles in the region of temperatures at and about the critical point, T>=T_c. Now we present a description of the behavior of the system at the critical point T_c, η_c) and in the region below the critical point. The calculation is carried out from the first principles. The expression for the grand canonical partition function is brought to the functional integrals defined on the set of collective variables. The Ising-like form is singled out. Below T_c, when a gas-liquid system undergoes a phase transition of the first order, i.e., boiling, a "jump" occurs from the "extreme" high probability gas state to the "extreme" high probability liquid state, releasing or absorbing the latent heat of the transition. The phase equilibria conditions are also derived.

【 授权许可】

Unknown