Oxidovanadium(V) and Dioxidomolybdenum(VI) Complexes of N'-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide: Synthesis, Characterization, Crystal Structures and Catalytic Property

Acta Chimica Slovenica

Ya-Fang Ye¹  Xiao-Ling Zou¹  Luo-Ju Yang¹  Huan-Yu Liu¹  Yi-Shu Yin¹ 

[1] a School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, P.R. Chinab Guangdong Cosmetics Engineering and Technology Research Center, Zhongshan 528458, P.R. China;

关键词: hydrazone;    vanadium complex;    molybdenum complex;    crystal structure;    catalytic property;   

DOI  :  10.17344/acsi.2019.5286

来源: DOAJ

【 摘 要 】

N'-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide (H2L) was used to prepare oxidovanadium(V) complex [VOL(OEt)(MeOH)] (1) and dioxidomolybdenum(VI) complex [MoO2L(OH2)]·[MoO2L(EtOH)] (2). The complexes were characterized by IR, UV-Vis, NMR spectroscopy, and single crystal X-ray diffraction. X-ray analysis indicates that the complexes are mononuclear species with the metal atoms in octahedral coordination. The complexes were studied for catalytic oxidation property on some olefins with tert-butyl hydroperoxide as oxidant.

【 授权许可】

Unknown