Crystal structure of 2-{(E)-[(2-hydroxyphenyl)iminiumyl]methyl}-4-methylphenolate

Acta Crystallographica Section E: Crystallographic Communications

Suresh Shalini¹  T. V. Venkatesha²  C. D. Sathish³  Mukesh M. Jotani⁴  C. R. Girija⁵ 

[1] Chemistry Research Centre (Affiliated to Kuvempu University), SSMRV Degree College, Jayanagar 4th T Block, Bangalore 560 041, Karnataka, India;Department of Chemistry, Jnana Sahyadri, Kuvempu University, Shankaragatta 577 451, India;Department of Chemistry, PESIT, BSK III Stage, Bangalore 560 085, India;Department of Physics, Bhavans Sheth R. A. College of Science, Khanpur, Ahmedabad 380 001, Gujarat, India;Govt. Science College, Nrupatunga Road, Ambedkar Veedhi, Sampangi Rama Nagar, Bengaluru 560 001, Karnataka, India;

关键词: crystal structure;    Schiff base;    N-(salicylidene)aniline;    zwitterion;    hydrogen bonding;   

DOI  :  10.1107/S2056989015006374

来源: DOAJ

【 摘 要 】

The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N—H...O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O—H...O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

【 授权许可】

Unknown