Rational design of MnS nanoparticles anchored on N,S-codoped carbon matrix as anode for lithium-ion batteries

Progress in Natural Science: Materials International

Yijing Wang¹  Yafei Liu²  Huinan Guo²  Weiqin Li²  Mengyuan Yue²  Kai Chen²  Zhaoxia Yuan²  Juming Gu³ 

[1] Corresponding author.;Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071, China;Quick Gem Optoelectronic S and T Co., Ltd., Langfang, 065001, China;

关键词: N,S-codoped;    MnS;    Nanocomposites;    Rods-like;    Lithium ion batteries;   

DOI  :  

来源: DOAJ

【 摘 要 】

The manganese sulfide (MnS) has attracted more attention as anode material on energy storage and conversion field, owing to its high theoretical capacity (616 ​mA ​h ​g−1) and good electrochemical activity. However, low electronic conductivity and large volume expansion during charge-discharge processes have limited its further application. In order to address above mentioned problems, the composites, MnS nanoparticles embedded in N,S-codoped porous carbon skeleton (named as MnS/N,S–C composites), herein have been prepared successfully using metal organic framework (Mn-NTA) as template. The porous carbon skeleton not only can enhance electrode conductivity, but also relieve volume expansion during charge-discharge processes. Thus, the rational design towards electrode architectures has endowed MnS/N,S–C nanocomposites with superior electrochemical performance, which delivers the specific capacities of 676.7 ​mA ​h ​g−1 at the current density of 100 ​mA ​g−1.

【 授权许可】

Unknown