Phenol Abatement by Titanium Dioxide Photocatalysts: Effect of The Graphene Oxide Loading

Nanomaterials

Usuma Naknikham¹  Vittorio Boffa¹  Yuanzheng Yue¹  PeterKjær Kristensen²  Giuliana Magnacca³  Ang Qiao⁴ 

[1] Department of Chemistry and Bioscience, Aalborg University, 9220 Aalborg, Denmark;Department of Physics and Nanotechnology, Aalborg University, 9220 Aalborg, Denmark;Dipartimento di Chimica, Universitá di Torino, 10125 Torino, Italy;State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China;

关键词: photocatalytic activity;    water purification;    TiO₂;    Graphene;    reproducibility;   

DOI  :  10.3390/nano9070947

来源: DOAJ

【 摘 要 】

Hetero-photocatalytic graphene-TiO₂ materials have, in the literature, been found to possess better photocatalytic activity for environmental applications compared to pure TiO₂. These types of materials can be prepared in different ways; however, their photocatalytic performance and quality are not easily controlled and reproduced. Therefore, we synthetized graphene oxide-TiO₂ nanoparticles by sol-gel reaction from TiCl₄, as precursor, with two different methods of synthesis and with a graphene oxide (GO) loading ranging from 0 to 1.0. This approach led to a good adhesion of GO to TiO₂ through the Ti-O-C bonding, which could enhance the photocatalytic performances of the materials. Overall, 0.05 wt % GO loading gave the highest rate in the photodegradation of phenol under visible light, while higher GO loadings had a negative impact on the photocatalytic performances of the composites. The 0.05 wt % GO-TiO₂ composite material was confirmed to be a promising photocatalyst for water pollutant abatement. The designed synthetic approach could easily be implemented in large-scale production of the GO-TiO₂ coupling materials.

【 授权许可】

Unknown