Recent Advances in Crystalline Oxidopolyborate Complexes of d-Block or p-Block Metals: Structural Aspects, Syntheses, and Physical Properties

Molecules

Ming-Hua Zhou¹  Chun-Yang Pan¹  Shu-Sheng Xin¹  Michael A. Beckett² 

[1] School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;School of Natural Sciences, Bangor University, Bangor LL57 2UW, UK;

关键词: borates;    coordination compounds;    inorganic–organic hybrids;    oxidoborate ligands;   

DOI  :  10.3390/molecules26133815

来源: DOAJ

【 摘 要 】

Crystalline materials containing hybrid inorganic–organic metal borates (complexes with oxidoborate ligands) display a variety of novel framework building blocks. The structural aspects of these hybrid metallaoxidoborates containing Cd^(II), Co^(II), Cu^(II), Ga^(III), In^(III), Mn^(II), Ni^(II) or Zn^(II) metal centers are discussed in this review. The review describes synthetic approaches to these hybrid materials, their physical properties, their spectroscopic properties and their potential applications.

【 授权许可】

Unknown