Obtaining Mn-Co Alloys in AISI 430 Steel from Lithium-Ion Battery Recycling: Application in SOFC Interconnectors

ChemEngineering

Sicele L. A. Gonçalves¹  Tulio Matencio²  Hosane A. Tarôco³  Eric M. Garcia³ 

[1] Department of Chemical Engineering, Federal University of Minas Gerais, Belo Horizonte 13565-905, Brazil;Department of Chemistry, Federal University of Minas Gerais, Belo Horizonte 13565-905, Brazil;Department of Exact and Biological Sciences, Federal University of São João Del Rei - Sete Lagoas Campus, Sete Lagoas 35701-970, Brazil;

关键词: interconnectors;    sofc;    chromium volatility;   

DOI  :  10.3390/chemengineering4010010

来源: DOAJ

【 摘 要 】

The recycling of exhausted lithium-ion batteries from mobile phones originate five solutions with different Co and Mn proportions that were used as electrolytic solutions to obtain Mn-Co spinel coatings on the surface of AISI430 stainless steel. The coatings are intended to contain chromium volatility in the working conditions of Solid Oxide Fuel Cells (SOFC) metallic interconnectors. Potentiostatic electrodeposition was the technique used to obtain Mn-Co coatings from low concentration electrolytes at pH = 3.0 and potential applied −1.3 V. Charge efficiency data were used for sample optimization. Three optimized samples were subjected to oxidation heat treatment at 800 °C for 300 h and then characterized by XRD, SEM and EDS. The results showed that the addition of manganese ions instead of cobalt ions in the electrolytic bath produces more stable and well-distributed deposits as the ratio of the two ions becomes equal in the electrolytic bath. Thin, homogeneous and stable spinel coatings (Mn, Co)₃O₄ 2.8 μm and 3.9 μm thick were able to block chromium volatility when exposed to SOFC operating temperature.

【 授权许可】

Unknown