Crystal structure of dichloridobis[2-(phenyldiazenyl)pyridine-κN1]zinc

Acta Crystallographica Section E: Crystallographic Communications

Nararak Leesakul¹  Saowanit Saithong¹  Kittipong Chainok²  Luksamee Vittaya³ 

[1] Department of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;Department of Physics, Faculty of Science and Technology, Thammasat University, Khlong Luang, Pathum Thani 12121, Thailand;Faculty of Science and Fisheries Technology, Rajamangala University of Technology Srivijaya, Sikao, Trang 92150, Thailand;

关键词: crystal structure;    zinc complex;    C—H...Cl interactions;   

DOI  :  10.1107/S2056989015019143

来源: DOAJ

【 摘 要 】

The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyldiazenyl)pyridine ligands coordinating to a central ZnII dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetrahedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bisecting the zinc cation. The structure is stabilized by weak intermolecular C—H...Cl interactions [C...Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring molecules into layers perpendicular to the c axis.

【 授权许可】

Unknown