Magnetic properties of nanostructured SiOo2:Eu3+ powders

Journal of the Serbian Chemical Society

Jokanović Vukoman¹  Spasojević Vojislav¹  Tadić Marin²  Andrić Željka²  Blanuša Jovan²  Mitrić Miodrag²  Kapičić Ana²  Dramićanin Miroslav²  Kusigerski Vladan² 

[1] Institut tehničkih nauka SANU, Beograd;Institut za nuklearne nauke 'Vinča', Beograd;

关键词: magnetic properties;    nanoparticles;    rare earth;    silica;    light scattering;   

DOI  :  10.2298/JSC0604413S

来源: DOAJ

【 摘 要 】

Eu-doped silica nanoparticles with different concentrations of europium (3% 6%and 15at.%) were prepared by a hydrothermal procedure. Light scattering measurements of the silica colloids as well as TEM microscopy, revealed a narrow size distribution of the particles, ranging from 5 to 10 nm. X-Ray diffraction showed that all the powders were amorphous. Magnetic susceptibility vs. temperature measurements showed a behavior typical for Eu3+ ions, with a plateau below 60K, and an increase of the mass susceptibility with Eu concentration. The splitting of zero-field cooled (ZFC) and field-coled (FC) susceptibility branches increased with the europium concentration, indicating the presence of interparticle interactions. At temperatures below 40K, a contribution of paramagnetic impurities obeying the Curie law was observed. Heat treatment of the powders at 823K and 1073K increased the magnetic susceptibility. The appearance of a small peak at 70K indicated the presence of small quantities of ferromagnetic EuO in the powders after heating.

【 授权许可】

Unknown