期刊论文详细信息
Molecules | |
Synthesis of Endohedral Metallofullerene Glycoconjugates by Carbene Addition | |
关键词: chemical functionalization; La2@Ih-C80; carbohydrate; diazirine; glycoconjugate; | |
DOI : 10.3390/molecules16119495 | |
来源: DOAJ |
【 摘 要 】
Endohedral metallofullerene glycoconjugates were synthesized under mild conditions by carbene addition using appropriate glycosylidene-derived diazirine with La2@Ih-C80. NMR spectroscopic studies revealed that the glycoconjugate consists of two diastereomers of [6,6]-open mono-adducts. The electronic properties were characterized using Vis/NIR absorption spectroscopy and electrochemical measurements. This study demonstrates that glycosylidene carbene is useful to incorporate carbohydrate moieties onto endohedral metallofullerene surfaces.
【 授权许可】
Unknown