Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines

Molecules

SultanT. Abu-Orabi¹  MariaA. F. Faustino²  MariaG. P. M. S. Neves²  AnaR. L. Araújo²  MárioM. Q. Simões²  NunoM. M. Moura²  JoséA. S. Cavaleiro²  AugustoC. Tomé²  CarlaI. M. Santos² 

[1] Chemistry Department, Yarmouk University, Irbid 211-63, Jordan;LAQV-REQUIMTE, Department of Chemistry, University of Aveiro,3810-193 Aveiro, Portugal;

关键词: azides;    phthalocyanines;    subphthalocyanines;    porphyrazines;    click chemistry;    photodynamic therapy;   

DOI  :  10.3390/molecules25071745

来源: DOAJ

【 摘 要 】

The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step.

【 授权许可】

Unknown