Trends of Ground-Level Ozone in New York City Area during 2007–2017

Atmosphere

Subraham Singh¹  Ilias G. Kavouras¹ 

[1] Department of Environmental, Occupational and Geospatial Health Sciences, City University of New York Graduate School of Public Health and Health Policy, 55 West 125th Street, New York, NY 10027, USA;

关键词: annual trend;    day-of-the-week variation;    ozone precursors;    urban environment;    wildfires;   

DOI  :  10.3390/atmos13010114

来源: DOAJ

【 摘 要 】

The spatiotemporal patterns of ground level ozone (O₃) concentrations in the New York City (NYC) metropolitan region for the 2007–2017 period were examined conjointly with local emissions of O₃ precursors and the frequency of wildfires. Daily 8-h and 1-h O₃ and nitric oxide (NO) concentrations were retrieved from the US Environmental Protection Agency (EPA) Air Data. Annual emission inventories for 2008 and 2017 were acquired from EPA National Emissions Inventory (NEI). The number and area burnt by natural and human-ignited wildfires were acquired from the National Interagency Fire Center (NIFC). The highest daily 8-h max O₃ concentrations varied from 90 to 111 parts per billion volume (ppbv) with the highest concentrations measured perimetrically to NYC urban agglomeration. The monthly 8-h max O₃ levels have been declining for most of the peri-urban sites but increasing (from +0.18 to +1.39 ppbv/year) for sites within the urban agglomeration. Slightly higher O₃ concentrations were measured during weekend than those measured during the weekdays in urban sites probably due to reduced O₃ titration by NO. Significant reductions of locally emitted anthropogenic nitrogen oxides (NO_x) and volatile organic compounds (VOCs) may have triggered the transition from VOC-limited to NO_X-limited conditions, with downwind VOCs sources being critically important. Strong correlations between the monthly 8-h max O₃ concentrations and wildfires in Eastern US were computed. More and destructive wildfires in the region were ignited by lightning for years with moderate and strong La Niña conditions. These findings indicate that climate change may counterbalance current and future gains on O₃ precursor’s reductions by amending the VOCs-to-NO_x balance.

【 授权许可】

Unknown