A novel strategy towards cyclic aliphatic (co)polyesters

eXPRESS Polymer Letters

关键词: Polymer synthesis, molecular e;    Ring-opening polymerization;    Cyclic polyesters;    Click chemistry;    Amphiphilic macrocycles;   

DOI  :  10.3144/expresspolymlett.2013.66

来源: DOAJ

【 摘 要 】

This feature article focuses on a novel strategy towards macrocyclic (co)polyesters that combines controlled ring-opening polymerization of lactones initiated by a cyclic tin(IV) dialkoxide and intramolecular cyclization by photocross-linking of pendant unsaturations next to the propagating sites. No linear species is ever involved in the polymerization and permanent cyclization steps, which allows higher molecular weight macrocycles to be prepared with high efficiency and no need for further purification. Moreover, this synthetic route is very flexible to the point where macrocyclic polyesters with more complex although well-defined architectures, such as tadpole-shaped and sun-shaped copolyesters, can be tailored. Synthesis of well-defined eight-shaped polyesters and twin tadpole-shaped copolymers has also been explored by using a spirocyclic tin(IV) alkoxides as an initiator. When functional lactones were introduced, the ‘click’ copper-mediated cycloaddition [3+2] reaction was utilized to make the eight-shaped and twin tadpole-shaped copolyesters amphiphilic.

【 授权许可】

Unknown