Metylcyclohexane conversion to light olefins

Brazilian Journal of Chemical Engineering

C. MARCILLY¹  E. BENAZZI¹  H. CAUFFRIEZ¹  C.F. SCOFIELD² 

[1] Institut Français du pétrole;Universidade do Estado do Rio de Janeiro (UERJ);

关键词: zeolites;    methylcyclohexane;    hydrogen transfer;   

DOI  :  10.1590/S0104-66321998000200018

来源: DOAJ

【 摘 要 】

This study consists in the evaluation of the catalytic properties of zeolites with different structures in the conversion of methylcyclohexane to light olefins. Results obtained suggest that the steric constrictions of the catalysts used play an important role in hydrogen transfer reactions. Higher selectivities for light olefins (C3= and C4=) were observed for zeolites having more closed structures, like MFI and ferrerite, when compared to those having more open ones, like beta, omega and faujasite.

【 授权许可】

Unknown