Crystal structure and Hirshfeld surface analysis of dichlorido(methanol-κO)bis(2-methylpyridine-κN)copper(II)

Acta Crystallographica Section E: Crystallographic Communications

J. Prakasha Reddy¹ 

[1] Department of Chemistry, School of Sciences, Indrashil University, Rajpur, Gujarat, 382740, India;

关键词: crystal structure;    hydrogen bonding;    α-picoline;    coordination chemistry;   

DOI  :  10.1107/S2056989020014036

来源: DOAJ

【 摘 要 】

In the title complex, [CuCl2(C6H7N)2(CH3OH)], the copper atom is five-coordinated by two nitrogen atoms of 2-methylpyridine ligands, two chloro ligands and an oxygen atom of the methanol molecule, being in a tetragonal–pyramidal environment with N and Cl atoms forming the basal plane. In the crystal, complex molecules related by the twofold rotation axis are joined into dimeric units by pairs of O—H...Cl hydrogen bonds. These dimeric units are assembled through C—H...Cl interactions into layers parallel to (001).

【 授权许可】

Unknown