Experimental Identification of the Roles of Fe, Ni and Attapulgite in Nitroreduction and Dechlorination of p-Chloronitrobenzene by Attapulgite-Supported Fe/Ni Nanoparticles

Materials

Jing Liang¹  Junwen Wang²  Emmanuella Anang²  Xianyuan Fan²  Hong Liu² 

[1] College of Environmental Engineering, Nanjing Polytechnic Institute, Nanjing 210048, China;College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, China;

关键词: attapulgite-supported nFe/Ni nanoparticles;    attapulgite;    Fe;    Ni;    p-chloronitrobenzene;   

DOI  :  10.3390/ma15031254

来源: DOAJ

【 摘 要 】

The porous-material loading and noble-metal doping of nanoscale zero-valent iron (nFe) have been widely used as countermeasures to overcome its limitations. However, few studies focused on the experimental identification of the roles of Fe, the carrier and the doped metal in the application of nFe. In this study, the nitroreduction and dechlorination of p-chloronitrobenzene (p-CNB) by attapulgite-supported Fe/Ni nanoparticles (ATP-nFe/Ni) were investigated and the roles of Fe, Ni and attapulgite were examined. The contributions of Ni are alleviating the oxidization of Fe, acting as a catalyst to trigger the conversion of H₂ to H*(active hydrogen atom) and promoting electron transfer of Fe. The action mechanisms of Fe in reduction of -NO₂ to -NH₂ were confirmed to be electron transfer and to produce H₂ via corrosion. When H₂ is catalyzed to H* by Ni, the production H* leads to the nitroreduction. In additon, H* is also responsible for the dechlorination of p-CNB and its nitro-reduced product, p-chloroaniline. Another corrosion product of Fe, Fe²⁺, is incapable of acting in the nitroreduction and dechlorination of p-CNB. The roles of attapulgite includes providing an anoxic environment for nFe, decreasing nFe agglomeration and increasing reaction sites. The results indicate that the roles of Fe, Ni and attapulgite in nitroreduction and dechlorination of p-CNB by ATP-nFe/Ni are crucial to the application of iron-based technology.

【 授权许可】

Unknown