Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes

Journal of the Serbian Chemical Society

关键词: alkyne;    sulfide;    alkylsulfenyl chloride;    hydrozirconation;    synthesis;   

DOI  :  

来源: DOAJ

【 摘 要 】

Terminal alkynes react with Cp2Zr(H)Cl (Cp = h5-C5H5) to give organozirconium complexes, which are trapped with alkylsulfenyl chlorides to afford (E)-vinyl alkyl sulfides in good yield.

【 授权许可】

Unknown