Spectral Study of Pt (II), Cr (II) Polymeric Complexes of the LigandN- Crotonyl -2- Hydroxy-Phenylazomethine

Al-Khawarizmi Engineering Journal

Alyaa Esam Mahdi¹ 

[1] Department of Chemical Engineering / University Of Technology;

关键词: Schiff Base;    Polymeric Complexes;    Spectroscopic Methods;    Divalent Metals;   

DOI  :  

来源: DOAJ

【 摘 要 】

The polymeric complexes were obtained from the reaction of polymeric Schiff base.N-crotonyl-2-hydroxyphenylazomethine (HL), with divalent metals Pt (II), Cr (II). The modes of bonding and overall geometry of the complexes were determine through spectroscopic methods and compared with that reported from analogous monomeric ligand. This study revealed square planer geometry around the metal center for [Pt(L)Cl] and distorted octahedral geometry for Cr complex [Cr(L)Cl(H2O)2].

【 授权许可】

Unknown