Mitigating the Health Effects of Aqueous Cr(VI) with Iron-Modified Biochar

International Journal of Environmental Research and Public Health

Zhihong Zheng¹  Xiaohan Duan¹ 

[1] School of Water Conservancy, North China University of Water Resources and Electric Power, Zhengzhou 450046, China;

关键词: adsorption;    environmental health;    chromium;    ferric chloride;    traditional Chinese medicine residual;   

DOI  :  10.3390/ijerph19031481

来源: DOAJ

【 摘 要 】

A large amount of chromium (Cr) has entered the natural environment from the wastewater and waste residues, and the hexavalent (Cr(VI)) is highly poisonous, threatening the ecological environment and human health directly. In this study, iron-modified biochar was prepared using honeysuckle residue as raw material and the ferric chloride impregnation method. Batch Cr(VI) adsorption experiments were carried out using the modified honeysuckle-derived biochar (MHDB) as an adsorbent. The results indicate that a pH of 2 was best for the adsorption removal of Cr(VI) in the initial pH range of 2–10. The adsorption kinetic data fitted the pseudo-second-order model best out of the two models, and the Langmuir model was better than the Freundlich model to describe the adsorption process. Thermodynamic analysis indicated that the adsorption process of Cr(VI) on MHDB had an endothermic and spontaneous nature, and the increasing temperature was conducive to the adsorption. The main mechanisms of Cr(VI) adsorption might be the physical adsorption (electrostatic interactions) and chemical adsorption (ion exchange, the reduction of Cr(VI) to Cr(III)). The efficient adsorption of Cr(VI) makes MHDB a potential material for Cr(VI)-containing wastewater treatment. This study provides a feasible adsorption material for mitigating the environmental hazards of chromium, which has a certain reference value for protecting environmental health.

【 授权许可】

Unknown