Synthesis of allenic naphthalene derivatives

Bulletin of the Chemical Society of Ethiopia

关键词: Isomerisation;    Allenic derivatives of naphthalene;   

DOI  :  

来源: DOAJ

【 摘 要 】

Propargylic alcohol of naphthalene derivatives were synthesized and converted to the corresponding propargylic acetate using acetic anhydride. Reduction of the propargylic acetates by SmI₂ afforded allenes and acetylenes. Base-promoted isomerisation of acetylene formed allene in high yield.

【 授权许可】

Unknown