Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ2N,O)copper(II)

Acta Crystallographica Section E: Crystallographic Communications

Sofiane Bouacida¹  Ali Ourari²  Wassila Derafa²  Chahinaz Zoubeidi²  Hocine Merazig³ 

[1] Département Sciences de la Matière, Faculté des sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria;Laboratoire d'Electrochimie, d'Ingénierie Moléculaire et de Catalyse Redox (LEIMCR), Faculté des Sciences de l'Ingénieur, Université Farhat Abbas, Sétif 19000, Algeria;Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine 1, 25000 , Algeria;

关键词: crystal structure;    copper(II) complex;    C—H...π interactions;   

DOI  :  10.1107/S2056989015001309

来源: DOAJ

【 摘 要 】

In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the CuII cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—O and Cu—N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual molecules are packed in alternating zigzag layers parallel to (001). Weak C—H...π interactions exist between the molecules.

【 授权许可】

Unknown