Crystal structure of 7-bromo-2-(3-fluorophenyl)-1-(methylsulfinyl)naphtho[2,1-b]furan

Acta Crystallographica Section E

Hong Dae Choi¹  Uk Lee² 

[1]Department of Chemistry, Dongeui University, San 24 Kaya-dong, Busanjin-gu, Busan 614-714, Republic of Korea

[2]Department of Chemistry, Pukyong National University, 599-1 Daeyeon 3-dong, Nam-gu, Busan 608-737, Republic of Korea

关键词: crystal structure;    naphthofuran;    3-fluorobenzene;    C—H...O interactions;    C—Br...π interactions;   

DOI  :  10.1107/S160053681401808X

来源: DOAJ

【 摘 要 】

In the title compound, C19H11BrFO2S, the dihedral angle between the plane of the naphthofuran ring system [r.m.s. deviation = 0.043 (2) Å] and that of the 3-fluorobenzene ring is 39.32 (8)°. In the crystal, molecules are linked by C—H...O and C—Br...π [3.835 (1) Å] interactions into stacks along the c axis, forming a three-dimensional network. The F atom is disordered over two positions, with site-occupancy factors of 0.851 (3) and 0.149 (3).

【 授权许可】

Unknown