MoS2‐Coupled Carbon Nanosheets Encapsulated on Sodium Titanate Nanowires as Super‐Durable Anode Material for Sodium‐Ion Batteries

Advanced Science

Fangjun Cao¹  Daming Zhou²  Yutong Li³  Zhongtai Zhang³  Zilong Tang³  Shitong Wang³  Yong Yang⁴ 

[1] College of science Northwest A&F University Yangling Shaanxi 712100 China;School of Astronautics Northwestern Polytechnical University Xi'an Shanxi 710072 China;State Key Lab of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing 100084 China;State Key Lab of Solidification Processing Center of Advanced Lubrication and Seal Materials Northwestern Polytechnical University Xi'an Shaanxi 710072 China;

关键词: core–shell;    MoS2 nanosheets;    sodium titanate nanowires;    sodium‐ion batteries;    strong‐coupled carbon;   

DOI  :  10.1002/advs.201900028

来源: DOAJ

【 摘 要 】

Abstract There is an ever‐increasing demand for rechargeable batteries with fast charging, long cycling, high safety, and low cost in new energy storage systems. Herein, a heterogeneous architecture composed of MoS2‐coupled carbon nanosheets encapsulated on sodium titanate nanowires is developed and demonstrated as an advanced anode for sodium‐ion batteries (SIBs). Owing to the synergistic effects of ultrastable substrate of 1D sodium titanate (NTO) nanowires, high‐capacity promoter of 2D MoS2 nanosheets as well as the 2D conductive carbon matrix, the resulting 1D/2D–2D hybrid demonstrates excellent high‐rate capacity and super‐durable cyclability, delivering a stable capacity of up to 425.5 mAh g−1 at 200 mA g−1. Even at an ultrafast charging/discharging process within 80 s, the capacity can be maintained at 201 mAh g−1 after 16 000 cycles with only 0.0012% capacity loss per cycle, one of the best high‐rate capacities and cyclabilities for NTO‐based hybrid composites. The present work highlights the designing protocol of hierarchical nanoarchitectures with stable substrate and high‐capacity electrodes for next‐generation energy storage applications.

【 授权许可】

Unknown