The sodium chloride complex catena-poly[[{μ3-2-[bis(2-hydroxyethyl)amino]ethan-1-ol}sodium] chloride], N(CH2CH2OH)3·NaCl

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Vinusuya Gock¹  Christina Krabbe¹  Michael Lutter¹  Klaus Jurkschat¹ 

[1] Lehrstuhl für Anorganische Chemie II, Technische Universität Dortmund, 44221 Dortmund, Germany;

关键词: crystal structure;    sodium chloride;    amino alcohol;    hydrogen bridge;    graph-set analysis;   

DOI  :  10.1107/S2414314619002384

来源: DOAJ

【 摘 要 】

The reaction of sodium chloride with 2-[bis(2-hydroxyethyl)amino]ethan-1-ol results in the formation of the title salt {[Na{N(CH2CH2OH)3}]Cl}n. The polymeric structure is characterized by a sodium cation coordinated by one nitrogen and five oxygen atoms in a distorted octahedral environment. The resulting one-dimensional {—O—Na—O—Na—O}— coordination polymer extends parallel to [010] and is connected through the chloride counter-anion via O—H...Cl hydrogen bonding, giving rise to a two-dimensional supramolecular structure parallel to (001).

【 授权许可】

Unknown