Crystal structure of {[1′-(diphenylphosphino)ferrocenyl]methyl}dimethylammonium chloride monohydrate

Acta Crystallographica Section E: Crystallographic Communications

Martin Zábranský¹  Petr Štěpnička¹ 

[1] Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic;

关键词: crystal structure;    ferrocene;    amines;    phosphines;    structure elucidation;   

DOI  :  10.1107/S2056989017013408

来源: DOAJ

【 摘 要 】

Individual ions and the solvating water molecule constituting the structure of the title compound, [Fe(C8H13N)(C17H14P)]Cl·H2O, assemble into dimeric units located around crystallographic inversion centers via N—H...Cl and O—H...Cl hydrogen bonds. These discrete fragments are further interconnected into chains by C—H...O interactions. The disubstituted ferrocene core in the {[1′-(diphenylphosphino)ferrocenyl]methyl}dimethylammonium cation has an approximate synclinal eclipsed conformation and is tilted by 3.40 (11)°.

【 授权许可】

Unknown