Dibromido[N-(1-diethylamino-1-oxo-3-phenylpropan-2-yl)-N′-(pyridin-2-yl)imidazol-2-ylidene]palladium(II) dichloromethane monosolvate

IUCrData

Jinwei Yuan¹  Liangru Yang¹  Pu Mao¹  Qilin Liu¹  Yongmei Xiao¹ 

[1] College of Chemistry and Chemical engineering, Henan University of Technology, Zhengzhou 450001, People's Republic of China;

关键词: crystal structure;    imidazol-2-ylidene;    palladium;   

DOI  :  10.1107/S241431461900899X

来源: DOAJ

【 摘 要 】

In the molecule of the title N,N′-disubstituted imidazol-2-ylidene palladium(II) complex, [PdBr2(C21H24N4O)]·CH2Cl2, the palladium(II) atom adopts a slightly distorted square-planar coordination (r.m.s. deviation = 0.0145 Å), and the five-membered chelate ring is almost planar [maximum displacement = 0.015 (8) Å]. The molecular conformation is enforced by intramolecular C—H...Br hydrogen bonds. In the crystal, complex molecules and dichloromethane molecules are linked into a three-dimensional network by C—H...O and C—H...Br hydrogen bonds.

【 授权许可】

Unknown