Electronic conduction during the formation stages of a single-molecule junction

Beilstein Journal of Nanotechnology

Oren Tal¹  Tal Klein¹  Atindra Nath Pal¹  Ayelet Vilan¹ 

[1] Department of Chemical and Biological Physics, Weizmann Institute of Science, Rehovot 7610001, Israel,;

关键词: break junction;    electron–vibration interactions;    electronic transport;    inelastic electron tunneling spectroscopy;    molecular junction;    molecular vibration;    quantum interference;    shot noise;   

DOI  :  10.3762/bjnano.9.138

来源: DOAJ

【 摘 要 】

Single-molecule junctions are versatile test beds for electronic transport at the atomic scale. However, not much is known about the early formation steps of such junctions. Here, we study the electronic transport properties of premature junction configurations before the realization of a single-molecule bridge based on vanadocene molecules and silver electrodes. With the aid of conductance measurements, inelastic electron spectroscopy and shot noise analysis, we identify the formation of a single-molecule junction in parallel to a single-atom junction and examine the interplay between these two conductance pathways. Furthermore, the role of this structure in the formation of single-molecule junctions is studied. Our findings reveal the conductance and structural properties of premature molecular junction configurations and uncover the different scenarios in which a single-molecule junction is formed. Future control over such processes may pave the way for directed formation of preferred junction structures.

【 授权许可】

Unknown