Hg2+ Optical Fiber Sensor Based on LSPR Generated by Gold Nanoparticles Embedded in LBL Nano-Assembled Coatings

Sensors

Javier Goicoechea¹  MaríaElena Martínez-Hernández¹  FranciscoJ. Arregui¹ 

[1] Department of Electrical, Electronic and Communication Engineering, Universidad Publica de Navarra, Edif. Los Tejos, Campus Arrosadía, 31006 Pamplona, Spain;

关键词: fiber optic sensor;    gold nanoparticles;    localized surface plasmon resonance;    mercury;    ppb;   

DOI  :  10.3390/s19224906

来源: DOAJ

【 摘 要 】

Mercury is an important contaminant since it is accumulated in the body of living beings, and very small concentrations are very dangerous in the long term. This paper reports the fabrication of a highly sensitive fiber optic sensor using the layer-by-layer nano-assembly technique with gold nanoparticles (AuNPs). The gold nanoparticles were obtained via a water-based synthesis route that use poly acrylic acid (PAA) as stabilizing agent, in the presence of a borane dimethylamine complex (DMAB) as reducing agent, giving PAA-capped AuNPs. The sensing mechanism is based on the alteration of the Localized Surface Plasmon Resonances (LSPR) generated by AuNPs thanks to the strong chemical affinity of metallic mercury towards gold, which lead to amalgam alloys.

【 授权许可】

Unknown