Lithium dilution in Li-Sn alloys

Nuclear Materials and Energy

A.C. Ferro¹  M.B. Costa²  M. Guedes³  E. Alves⁴  L.C. Alves⁴  R. Mateus⁵ 

[1] CDP2T and Dep. Mech. Engineering, Setúbal School of Technology, IP Setúbal, 2910-761 Setúbal, Portugal;Corresponding author.;C2TN, Instituto Superior Técnico, ULisboa, 2695-066 Bobadela, Portugal;CeFEMA, Instituto Superior Técnico, ULisboa, 1049-001 Lisboa, Portugal;IPFN, Instituto Superior Técnico, ULisboa, 1049-001 Lisboa, Portugal;

关键词: Li-Sn alloys;    Low Li content;    Homogeneity;    Sn-rich intermetallics;   

DOI  :  

来源: DOAJ

【 摘 要 】

Liquid lithium-tin (Li-Sn) alloys are being considered in alternative concepts of plasma facing components for nuclear fusion applications. Nevertheless, the high Li content and high melting temperature of Li-rich intermetallics may hinder their use due to a possible excessive evaporation of Li to the vessel with evident issues in fuel retention. Their formation was inhibited in this study in homogeneous alloys with Li contents as higher as 5 at.% via a mechanical alloying route of pure Li and Sn sources. A 50 at.% Li-Sn master powder was initially prepared and diluted afterwards with pure Sn to achieve the final compositions. The structure, elemental composition and homogeneity of the alloys were assessed by scanning electron microscopy, ion beam analysis and X-ray diffraction. 5 at.% Li and 1 at.% Li alloys composed by phases with low melting temperatures, LiSn, Li2Sn5 and β-Sn, mainly, were produced with reduced oxygen and metallic impurity contents.

【 授权许可】

Unknown