期刊论文详细信息
Journal of the Brazilian Chemical Society
Electrochemical energy conversion: methanol fuel cell as example
关键词: energy conversion;    electrocatalysis;    fuel cell system;    methanol oxidation;    reaction pathways;   
DOI  :  
来源: DOAJ
【 摘 要 】

Thermodynamic and kinetic limitations of the electrochemical energy conversion are presented for the case of a methanol/oxygen fuel cell. The detection of intermediates and products is demonstrated using insitu FTIR spectroscopy and online mass spectrometry. The bifunctional catalysis of methanol oxydation by PtRu model surfaces is explained. The formation of HCOOH and HCHO via parallel reaction pathways is discussed. An example of DMFC system technology is presented.

【 授权许可】

Unknown   

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