Crystal structure and Hirshfeld surface analysis of (E)-3-(benzylideneamino)-5-phenylthiazolidin-2-iminium bromide

Acta Crystallographica Section E: Crystallographic Communications

Mehmet Akkurt¹  Taras Chyrka²  Gunay Z. Mammadova³  Gulnara Sh. Duruskari³  Abel M. Maharramov³ 

[1] Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey;Department of Theoretical and Industrial Heat Engineering (TPT), National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", 03056, Kyiv, Ukraine;Organic Chemistry Department, Baku State University, Z. Xalilov str. 23, Az, 1148 Baku, Azerbaijan;

关键词: crystal structure;    charge assisted hydrogen bonding;    thiazolidine ring;    envelope conformation;    hirshfeld surface analysis;   

DOI  :  10.1107/S2056989020001899

来源: DOAJ

【 摘 要 】

The central thiazolidine ring of the title salt, C16H16N3S+·Br−, adopts an envelope conformation, with the C atom bearing the phenyl ring as the flap atom. In the crystal, the cations and anions are linked by N—H...Br hydrogen bonds, forming chains parallel to the b-axis direction. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H...H (46.4%), C...H/H...C (18.6%) and H...Br/Br...H (17.5%) interactions.

【 授权许可】

Unknown