Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

Metals

Radovan Herchel¹  Ivan Nemec¹  Ingrid Svoboda² 

[1] Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 1192/12, 771 46 Olomouc, Czech Republic;Material sciences, Darmstadt University of Technology, D-64287 Darmstadt, Germany;

关键词: spin crossover;    Schiff base ligands;    iron (III) complex;    structure;    magnetism;   

DOI  :  10.3390/met9080849

来源: DOAJ

【 摘 要 】

The synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA²⁻ is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations.

【 授权许可】

Unknown