Synthesis of electrocatalysts by the Bönnemann method for the oxidation of methanol and the mixture H2/CO in a Proton Exchange Membrane Fuel Cell

Journal of the Brazilian Chemical Society

关键词: electrocatalyst;    fuel cell;    methanol oxidation;    reformate gas;   

DOI  :  

来源: DOAJ

【 摘 要 】

The synthesis of ternary electrocatalysts Pt/Ru/Mo type were performed according to the Bönnemann method and characterized by the following techniques: energy dispersive analysis (EDX), X-rays diffraction (XRD), cyclic voltammetry (CV) and polarization curves (E vs. i) for the oxidation of H2, H2/CO and methanol in a Proton Exchange Membrane Fuel Cell (PEMFC). Catalysts structure consists of highly dispersed nanocrystals in carbon support, with an average particle size of 2 nm. The results of cyclic voltammetry suggest an enhancement of the catalyst electroactivity with the addition of cocatalysts. Polarization curves indicate that Pt/Ru/Mo systems could be employed as electrode material for PEM fuel cell for technological application.

【 授权许可】

Unknown