Adsorption Kinetics and Thermodynamics of Cellulose Dinitrobenzoate Prepared in Ionic Liquid for the Removal Of Creatinine

BioResources

Feng Peng¹  Junli Ren¹  Qingqing Dai²  Weiqing Kong²  Ling Meng² 

[1] China;South China University of Technology;

关键词: Cellulose;    Cellulose dinitrobenzoate;    Ionic liquids;    Adsorption;    Creatinine;   

DOI  :  10.15376/biores.10.2.3666-3681

来源: DOAJ

【 摘 要 】

Creatinine is one of the major toxins in patients suffering from chronic renal failure. In this paper, cellulose dinitrobenzoate, with a degree of substitution (DS) of 0.15, was used as an oral adsorbent for creatinine adsorption. Cellulose dinitrobenzoate was prepared by modification of cellulose with 3,5-dinitrobenzoyl chloride in 1-butyl-3-methylimidazolium chloride (BMIMCl) ionic liquid as a homogenous medium. The effects of contact time, pH, adsorption temperature, and initial concentration of creatinine on the adsorption per unit mass of cellulose dinitrobenzoate were studied, comparatively. Results showed that the maximum adsorption per unit mass for creatinine was 3.88 mg/g. Furthermore, the adsorption process was spontaneous and exothermic. It was determined that the experimental results were well fitted to the pseudo-second-order rate equation and the Freundlich adsorption isotherm. Compared with traditional oral adsorbents, this cellulose-based adsorbent was biocompatible and could remove creatinine from dialysate effectively.

【 授权许可】

Unknown