Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)methyl]-2-(thiazol-4-yl)-1H-benzimidazole

Acta Crystallographica Section E: Crystallographic Communications

Mohamed Saadi¹  Lahcen El Ammari¹  El Mokhtar Essassi²  Rachid Bouhfid²  Hicham Gueddar² 

[1] Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V de Rabat, Avenue Ibn Battouta, BP 1014, Rabat, Morocco;Moroccan Foundation for Advanced Science, Innovation and Research (MASCIR), Rabat, Morocco;

关键词: crystal structure;    benzimidazole;    thiazol-4-yl;    1,3-dioxolan-4-yl;   

DOI  :  10.1107/S205698901502085X

来源: DOAJ

【 摘 要 】

The benzimidazole ring in the title compound, C16H17N3O2S, is almost planar, with the greatest deviation from the mean plane being 0.032 (1) Å. The fused-ring system makes dihedral angles of 19.91 (7) and 24.51 (8)° with the best plane through each of the thiazol-4-yl and 1,3-dioxolan-4-yl rings, respectively; the latter exhibits an envelope conformation with the methylene C atom being the flap. Finally, the thiazol-4-yl ring makes a dihedral angle of 33.85 (9)° with the 1,3-dioxolan-4-yl ring. In the crystal, molecules are connected by a pair of C—H...π(imidazole) interactions to form centrosymmetric aggregates.

【 授权许可】

Unknown