Crystal structure of N,N′-bis[(pyridin-4-yl)methyl]naphthalene diimide

Acta Crystallographica Section E

Diego Martínez-Otero¹  Mariana Nicolas-Gomez¹  Alejandro Dorazco-González¹ 

[1] Centro Conjunto de Investigacion en Quimica Sustentable UAEM-UNAM, Instituto de Quimica, Universidad Nacional Autonoma de Mexico, Carretera Toluca-Atlacomulco Km 14.5 CP 50200 Toluca, Estado de Mexico, Mexico;

关键词: crystal structure;    naphthalene diimide;    transistors;    organic supramolecular solids;    hydrogen bonding;    π–π stacking;   

DOI  :  10.1107/S1600536814017917

来源: DOAJ

【 摘 要 】

In the centrosymmetric title compound, C26H16N4O4 {systematic name: 6,13-bis[(pyridin-4-yl)methyl]-6,13-diazatetracyclo[6.6.2.04,16011,15]hexadeca-1,3,8,10,15-pantaene-5,7,12,14-tetrone}, the central ring system is essentially planar [maximum deviation = 0.0234 (8) Å] and approximately perpendicular to the terminal pyridine ring [dihedral angle = 84.38 (3)°]. The molecules displays a trans conformation with the (pyridin-4-yl)methyl groups on both sides of the central naphthalene diimide plane. In the crystal, molecules are linked by π–π stacking between parallel pyridine rings [centroid–centroid distances = 3.7014 (8) and 3.8553 (8) Å] and weak C—H...O hydrogen bonds, forming a three-dimensional supramolecular architecture.

【 授权许可】

Unknown