Crystal structure of 2-[2-phenyl-1-(phenylsulfonyl)ethyl]-1-phenylsulfonyl-1H-indole

Acta Crystallographica Section E: Crystallographic Communications

Arasambattu K. Mohanakrishnan¹  Potharaju Raju¹  G. Chakkaravarthi²  R. Yamuna³  M. Umadevi⁴ 

[1] Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India;Department of Physics, CPCL Polytechnic College, Chennai 600 068, India;Department of Sciences, Chemistry and Materials Research Lab, Amrita Vishwa Vidyapeetham University, Ettimadai, Coimbatore 641 112, India;Research and Development Centre, Bharathiyar University, Coimbatore 641 046, India;

关键词: crystal structure;    indole;    hydrogen bonding;    C—H...π interactions;   

DOI  :  10.1107/S2056989015019428

来源: DOAJ

【 摘 要 】

In the title compound, C28H23NO4S2, the indole ring system (r.m.s. deviation = 0.007 Å) subtends dihedral angles of 78.69 (13) and 38.97 (13)° with the planes of the N- and C-bonded sulfonylbenzene rings, respectively, and these two benzene rings are inclined to each other at an angle of 65.45 (16)°. The methylene-linked phenyl ring is twisted at an angle of 81.80 (13)° from the indole ring. The molecular structure features two short intramolecular C—H...O contacts, which both generate S(6) rings. In the crystal, molecules are linked by C—H...O hydrogen bonds and C—H...π interactions, generating a three-dimensional network.

【 授权许可】

Unknown