fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chloride

IUCrData

Sylvain Bernès¹  Mouhamadou Birame Diop²  Libasse Diop² 

[1] Instituto de Física, Benemérita Universidad Autónoma de Puebla, Av. San Claudio y 18 Sur, 72570 Puebla, Pue., Mexico;Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal;

关键词: crystal structure;    cobalt;    nitrate;    2,2′-bipyridine;    supramolecular interactions;   

DOI  :  10.1107/S2414314618008660

来源: DOAJ

【 摘 要 】

The asymmetric unit of the title complex, [Co(NO3)(C10H8N2)(H2O)3]Cl, consists of a chloride anion and a complex cation, which is built on a monodentate nitrate anion, three water molecules and one bidentate 2,2′-bipyridine molecule, coordinated to a CoII cation, in a distorted octahedral geometry. The water molecules are arranged in a facial geometry, and serve as donors for hydrogen bonding. Acceptor sites in the crystal are chloride ions and one O atom of the coordinating nitrate ion. A three-dimensional framework is formed, based on O—H...O and O—H...Cl contacts.

【 授权许可】

Unknown