Deformation Properties of Concentrated Metal-in-Polymer Suspensions under Superimposed Compression and Shear

Polymers

Alexander Ya. Malkin¹  Valery G. Kulichikhin¹  Anton V. Mityukov¹  Sergey V. Kotomin¹ 

[1] Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119919 Moscow, Russia;

关键词: concentrated suspensions;    viscoelasticity;    viscoplasticity;    squeezing;    shear stress;    compression;   

DOI  :  10.3390/polym12051038

来源: DOAJ

【 摘 要 】

Concentrated metal-in-polymer suspensions (55 and 60 vol.%) of aluminum powder dispersed in low molecular weight polyethylene glycol) demonstrate elastoplastic properties under compression and shear. The rheological behavior of concentrated suspensions was studied in a rotational rheometer with uniaxial compression (squeezing), as well as shearing superimposed on compression. At a high metal concentration, the elasticity of the material strongly increases under strain, compared with the plasticity. The elastic compression modulus increases with the growth of normal stress. Changes in the shear modulus depend on both normal and shear stresses. At a low compression force, the shear modulus is only slightly dependent on the shear stress. However, high compression stress leads to a decrease in the shear modulus by several orders with the growth of the shear stress. The decrease in the modulus seems to be rather unusual for compacted matter. This phenomenon could be explained by the rearrangement of the specific organization of the suspension under compression, leading to the creation of inhomogeneous structures and their displacement at flow, accompanied by wall slip. The obtained set of rheological characteristics of highly loaded metal-in-polymer suspensions is the basis for understanding the behavior of such systems in the powder injection molding process.

【 授权许可】

Unknown