Synthesis and structure of the dimericdiorganotinhydroxyphosphinate [t-Bu2Sn(OH)OPPh2O)]2

Main Group Metal Chemistry

Kather Ralf¹  Lork Enno¹  Beckmann Jens¹ 

[1] Institut für Anorganische Chemie und Kristallographie, Universität Bremen, Leobener Straße 7, 28359 Bremen, Germany;

关键词: hydrogen bonding;    hypercoordination;    phosphinate;    tin;    x-ray structure;   

DOI  :  10.1515/mgmc-2017-0017

来源: DOAJ

【 摘 要 】

The reaction of (C6F5)3BOPPh2OH (prepared in situ from the rather weak Brønsted acid Ph2PO2H and the strong Lewis acid B(C6F5)3) with (t-Bu2SnO)3 provided the dinuclear complex [t-Bu2Sn(OH)OPPh2O)]2, which was investigated by X-ray crystallography.

【 授权许可】

Unknown