Beilstein Journal of Organic Chemistry | |
The chemistry of amine radical cations produced by visible light photoredox catalysis | |
Theresa H. Nguyen1  Nan Zheng1  Jie Hu1  Jiang Wang1  | |
[1] Department of Chemistry, University of Arkansas, Fayetteville, AR 72701, USA; | |
关键词: α-amino radical; amine radical cation; catalysis; distonic ion; free radical; iminium ion; photoredox; visible light; | |
DOI : 10.3762/bjoc.9.234 | |
来源: DOAJ |
【 摘 要 】
Amine radical cations are highly useful reactive intermediates in amine synthesis. They have displayed several modes of reactivity leading to some highly sought-after synthetic intermediates including iminium ions, α-amino radicals, and distonic ions. One appealing method to access amine radical cations is through one-electron oxidation of the corresponding amines under visible light photoredox conditions. This approach and subsequent chemistries are emerging as a powerful tool in amine synthesis. This article reviews synthetic applications of amine radical cations produced by visible light photocatalysis.
【 授权许可】
Unknown