The chemistry of amine radical cations produced by visible light photoredox catalysis

Beilstein Journal of Organic Chemistry

Theresa H. Nguyen¹  Nan Zheng¹  Jie Hu¹  Jiang Wang¹ 

[1] Department of Chemistry, University of Arkansas, Fayetteville, AR 72701, USA;

关键词: α-amino radical;    amine radical cation;    catalysis;    distonic ion;    free radical;    iminium ion;    photoredox;    visible light;   

DOI  :  10.3762/bjoc.9.234

来源: DOAJ

【 摘 要 】

Amine radical cations are highly useful reactive intermediates in amine synthesis. They have displayed several modes of reactivity leading to some highly sought-after synthetic intermediates including iminium ions, α-amino radicals, and distonic ions. One appealing method to access amine radical cations is through one-electron oxidation of the corresponding amines under visible light photoredox conditions. This approach and subsequent chemistries are emerging as a powerful tool in amine synthesis. This article reviews synthetic applications of amine radical cations produced by visible light photocatalysis.

【 授权许可】

Unknown