Ruthenium Inlaying Porous Aromatic Framework for Hydrogen Generation From Ammonia Borane

Frontiers in Materials

Hao Ren¹  Peng Cui²  Guangshan Zhu² 

[1] Preparative Chemistry, College of Chemistry, Jilin University, Changchun, China;;State Key Laboratory of Inorganic Synthesis &

关键词: porous organic framework;    ionothermal reaction;    ammonia borane;    Ruthenium;    catalytic hydrolysis;   

DOI  :  10.3389/fmats.2019.00223

来源: DOAJ

【 摘 要 】

Porous organic frameworks (POFs) are a new family of porous materials, which are characterized by high chemical and thermal stabilities, structural design-abilities, chemical functionalities, high porosities, etc. Designable skeletons of POFs lead to different applications in many fields. Herein, we report a porous aromatic framework PAF-72 synthesized via ionothermal reaction. The inherently nitrogen contained skeleton of PAF-72 is beneficial for introducing catalytic active center Ruthenium, which is verified by ICP, TGA, and TEM element mapping. Besides, Ru/PAF-72 shows excellent activity in hydrogen generation from hydrolysis of ammonia borane and good cyclic performance.

【 授权许可】

Unknown