Detonation Nanodiamonds: A Comparison Study by Photoacoustic, Diffuse Reflectance, and Attenuated Total Reflection FTIR Spectroscopies

Nanomaterials

DmitryS. Volkov¹  MikhailA. Proskurnin¹  PetrK. Krivoshein¹ 

[1] Chemistry Department, Lomonosov Moscow State University, Moscow 119991, Russia;

关键词: detonation nanodiamonds;    photoacoustic IR spectroscopy;    diffuse-reflectance IR spectroscopy;    attenuated total internal reflection IR spectroscopy;   

DOI  :  10.3390/nano10122501

来源: DOAJ

【 摘 要 】

The qualitative analysis of nanodiamonds by FTIR spectrometry as photoacoustic (FTIR–PAS), diffuse-reflectance (DRIFT), and attenuated total reflection (ATR) modalities was evaluated for rapid and nondestructive analysis and comparison of nanodiamonds. The reproducibility and signal-gathering depth of spectra was compared. The assignment of characteristic bands showed that only six groups of bands were present in spectra of all the modalities with appropriate sensitivity: 1760 (C=O stretch, isolated carboxyl groups); 1640–1632 (H–O–H bend, liquid water); 1400–1370 (non-carboxyl C–O–H in-plane bend and CH₂ deformation); 1103 (non-carboxyl C–O stretch); 1060 (in-plane C–H bend, non-aromatic hydrocarbons and carbohydrates); 940 cm⁻¹ (out-of-plane carboxyl C–O–H bend). DRIFT provides the maximum number of bands and is capable of measuring hydrogen-bonded bands and CH_x groups. ATR provides the good sensitivity for water and C–H/C–C bands in the range 2000–400 cm⁻¹. FTIR–PAS reveals less bands than DRIFT but more intense bands than ATR–FTIR and shows the maximum sensitivity for absorption bands that do not appear in ATR-IR spectra and are expedient for supporting either DRIFT or FTIR–PAS along with depth-profiling. Thus, all three modalities are required for the full characterization of nanodiamonds surface functional groups.

【 授权许可】

Unknown