Me4PhPO3HSnCl4 AND (Me4N)2PhPO3SnBr4: SYNTHESIS AND INFRARED STUDY

Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry

HASSAN ALLOUCH¹  LIBASSE DIOP¹ 

[1] Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar Sénégal;

关键词: phenylphosphonate;    hydrogenophenylphosphonate;    bridging oxyanion;    octahedral environment;    supramolecular architecture;   

DOI  :  

来源: DOAJ

【 摘 要 】

The title adducts have been obtained on allowing Me4NPh2PO2 to react in specific ratios with SnX4 (X = Cl, Br). The infrared data allow to suggest an infinite chain structure, the anion behaving as a bridging ligand, the environment around tin IV being octahedral. In Me4NPhPO3H.SnX4 (X = Cl, Br) when the anion is involved through OH.....O or/and OH.....X hydrogen bonds a supramolecular architecture is obtained.

【 授权许可】

Unknown