Isolation and Characterization of Alpha and Nanocrystalline Cellulose from Date Palm (Phoenix dactylifera L.) Trunk Mesh

Polymers

Mohammad Asif Alam¹  Niyaz Ahamad Madhar²  Hamid M. Shaikh³  Anesh Manjaly Poulose³  Saeed M. Al-Zahrani³  Abdullah Alhamidi³  Arfat Anis³ 

[1] Center of Excellence for Research in Engineering Materials (CEREM), King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia;Department of Physics and Astronomy, College of Sciences, King Saud University, Riyadh 11451, Saudi Arabia;SABIC Polymer Research Center (SPRC), Department of Chemical Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia;

关键词: date palm trunk mesh;    cellulose;    lignocellulosic waste;    alpha cellulose;    nanocellulose;   

DOI  :  10.3390/polym13111893

来源: DOAJ

【 摘 要 】

Highly pure cellulosic polymers obtained from waste lignocellulose offer great potential for designing novel materials in the concept of biorefinery. In this work, alpha-cellulose and nanocrystalline cellulose were isolated from the date palm trunk mesh (DPTM) through a series of physicochemical treatments. Supercritical carbon dioxide treatment was used to remove soluble extractives, and concentrated alkali pretreatment was used to eliminate the lignin portion selectively to obtain alpha-cellulose in approximately 94% yield. Further treatments of this cellulose yielded nanocrystalline cellulose. The structure–property relationship studies were carried out by characterizing the obtained polymers by various standard methods and analytical techniques such as Fourier transform infrared spectroscopy-attenuated total reflection (FTIR-ATR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), energy dispersive X-ray diffraction (EDX-XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Almost 65% yield of pure cellulose was achieved, out of which 94% is the alpha-cellulose. This cellulose shows good thermal stability and crystallinity. The microscopic analysis of the nanocellulose showed a heterogeneous mix of irregular-shaped particles with a size range of 20–60 nm. The percentage crystallinity of alpha-cellulose and nanocellulose was found to be 68.9 and 71.8, respectively. Thus, this study shows that, this DPTM-based low-cost waste biomass can be a potential source to obtain cellulose and nano-cellulose.

【 授权许可】

Unknown